Hello tp4u
Almost certain if you have Windows 8.1 Pro on your system it's UEFI. Don't forget to also concern yourself with Secure Boot, both may or may not have to be disabled, depending on what you're doing with your system at any given time, including running a bootable suite of test tools. Point being,
almost always you'll need to disable at least Secure Boot, not always UEFI, to boot to something other than the HDD or SSD when performing some task.
Hit whatever key, F2... while the system is booting up, and go into the BIOS and first -->>
Disable Secure Boot (Advanced tab), then head to EXIT -->
don't Save & Exit, simply Save your changes... See if disabling secure boot opens up options not available while secure boot is enabled.
Pics of all BIOS tabs might help, or links to pics of a similar BIOS. It's impossible to know where everything is located on all systems without seeing the options available.
If you accidentally reboot to Windows 8.1 without secure boot enabled I don't think it will boot up, so make sure you're ready.
Don't worry, just re-enable secure boot if you need back into Windows 8.1... that's all.
Since your going to reinstall you need to grab from Toshiba all the documentation - manuals, setup guides, etc, while you're also grabbing your drivers. I'm sure the docs will spell out for you how to enter the BIOS and what to disable to get your system to boot from USB or DVD, this is a very common need and should be spelled out either in their docs, surely in their help forums.
Sorry, I forgot to add this link, does your BIOS look similar -> BIOS setup changes are necessary, if booting from external devices is required (Genuine Windows 8 units)
I'm lazy, I just noticed your pic, your BIOS is UEFI and Secure Boot is enabled (active)