You can move the special user folders, but it's better to leave them on a drive in the system. If you put them on an external drive, you'll need to carry that drive with you ALL the time.
The double Recovery partition is disconcerting - maybe KYHI has an answer.
Please launch an elevated Command prompt (right click command, select Run as administrator...)
enter the following commands
sel dis 1
sel par 2
*** before you exit Command Prompt grab a screenshot and post it - thanks